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Georgii I. Nikonov, Sergei F. Vyboishchikov, Oleg G. Shirobokov and Razvan Simionescu Serendipitous Metal-Catalyzed H–H/Si–H Exchange European Journal of Inorganic Chemistry 2014

Article first published online: 22 MAY 2014 | DOI: 10.1002/ejic.201402202

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Metal-catalyzed exchange between H2 and hydrosilanes occurs under conditions in which neither H–Si or H–H addition to metal nor σ-bond metathesis with the M–Si or M–H bonds take place, which suggests a novel way of activating dihydrogen.

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