Andreas Eich, Wilfried Hoffbauer, Gregor Schnakenburg, Thomas Bredow, Jörg Daniels and Johannes Beck Double-Cube-Shaped Mixed Chalcogen/Pentele Clusters from GaCl3 Melts European Journal of Inorganic Chemistry 2014
GaCl3-based melts are a suitable reaction medium for the synthesis of polycationic clusters. A series of double-cube-shaped mixed antimony–chalcogen clusters such as (Sb7Se8)5+ or (Sb7S8Cl2)3+ are synthesized and characterized by Raman and solid-state 77Se NMR spectroscopy. DFT calculations provide insights into the bonding situation and the spectroscopic properties.
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