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Javier Cepeda and Sonia Pérez-Yáñez Modulating the MII/Pyrimidine-4,6-dicarboxylato System by Metal, Solvent and Temperature Variation European Journal of Inorganic Chemistry 2014

Version of Record online: 12 JUN 2014 | DOI: 10.1002/ejic.201402269

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The pyrimidine-4,6-dicarboxilato ligand preferentially renders planar 1D motifs when coordinating to first-row divalent metal ions. This structural limitation has been avoided by focusing on three approaches that share a common aim: to modulate the coordination sphere by replacing/eliminating solvent molecules. A complete thermal characterisation and steric hindrance analysis is reported.

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