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Swarna Kamal Samanta, Sk Md Towsif Abtab, Pinki Saha Sardar, Sagarika Sanyal, Muktimoy Chaudhury and Sanjib Ghosh Role of Triplet States of Two Different Ligands in the Sensitized Emission of LnIII (EuIII, TbIII) in d–f Hybrid Tetranuclear Heterometal (ZnII2LnIII2, CdII2LnIII2) Complexes European Journal of Inorganic Chemistry 2014

Version of Record online: 3 JUN 2014 | DOI: 10.1002/ejic.201402274

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The d–f hybrid tetranuclear ZnII2LnIII2 and CdII2LnIII2 complexes, involving a pair of carboxylate ligands in a rare μ422: bridging mode, show synergistic “antenna effect”. The ZnII system shows enhanced “antenna effect” compared with the CdII analogue.

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