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Maria Pia Donzello, Giorgia De Mori, Elisa Viola, David Futur, Zhen Fu, Corrado Rizzoli, Luisa Mannina, Enrico Bodo, Maria Luisa Astolfi, Claudio Ercolani and Karl M. Kadish Experimental and DFT/Time-Dependent DFT Studies on Neutral and One-Electron-Reduced Quinoxaline and Pyrazine Precursors and Their Mononuclear (PdII, PtII) Derivatives European Journal of Inorganic Chemistry 2014

Version of Record online: 4 JUL 2014 | DOI: 10.1002/ejic.201402282

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6,7-Dicyano-2,3-di(2-pyridyl)quinoxaline, [(CN)2Py2Qx], its mononuclear complex [(CN)2Py2QxPtCl2] and the 2,3-dicyanopyrazine compounds [(CN)2Py2Pyz] and its PtII complex [(CN)2Py2PyzPtCl2], carrying 2-pyridyl rings were studied as neutral and mononegatively charged species by electrochemical and UV/Vis spectral measurements. The obtained data were interpreted by DFT/time-dependent DFT studies.

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