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Luca De Gioia, Catherine Elleouet, Sabrina Munery, François Y. Pétillon, Philippe Schollhammer, Jean Talarmin and Giuseppe Zampella Reductive Behavior of [Fe2(CO)4(κ2-dmpe){μ-(SCH2)2NBn}]: Effect of Symmetrization on the Rotated Conformation in FeI-FeI Models of [2Fe]H Subsite of [Fe-Fe]­H2ases European Journal of Inorganic Chemistry 2014

Article first published online: 4 JUL 2014 | DOI: 10.1002/ejic.201402335

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Electrosynthesis, through an electron-transfer-catalyzed process, and structural characterization of the symmetrical complex [Fe2(CO)4(μ-dmpe){μ-(SCH2)2NBn}] [dmpe = 1,2-bis(dimethylphosphino)ethane] afford straight experimental evidence that desymmetrization is required to promote an inverted pyramidal conformation in this class of model compounds of the [2Fe]H subsite of [Fe-Fe]H2ases.

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