Anne Grundmann, Menyhárt B. Sárosi, Peter Lönnecke and Evamarie Hey-Hawkins Organotantalum Phosphaketene and Phosphaazaallene Complexes European Journal of Inorganic Chemistry 2014
The first tantalum phosphaketene and phosphaazaallene complexes are obtained by insertion of carbon monoxide and cyclohexyl isocyanide into the Ta–P bond of cyclohexyl- and (isopropylphosphanylidene)tantalum(V) complexes. The phosphaazaallene complexes occur as E and Z isomers. These isomers have different electronic structures according to NMR spectroscopy studies and DFT calculations.
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