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Niveen M. Khashab, Ali Trabolsi, Yuen A. Lau, Michael W. Ambrogio, Douglas C. Friedman, Hussam A. Khatib, Jeffrey I. Zink and J. Fraser Stoddart Redox- and pH-Controlled Mechanized Nanoparticles European Journal of Organic Chemistry 2009

Version of Record online: 9 MAR 2009 | DOI: 10.1002/ejoc.200801300

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Ferrocene-based mechanized nanoparticles have been prepared, loaded with Rhodamine dye, and then capped with either β-cyclodextrin (top) or cucurbit[7]uril (bottom). Both of these systems were operated successfully under redox (oxidation of ferrocenedicarboxylic acid) control in the presence of β-cyclodextrin and under pH (deprotonation of ferrocenedicarboxylic acid at pH > 4) control in the presence of cucurbit[7]uril.

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