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Zhuang Jin, Bo Xu and Gerald B. Hammond Green Synthesis of Vicinal Dithioethers and Alkenyl Thioethers from the Reaction of Alkynes and Thiols in Water European Journal of Organic Chemistry 2010

Article first published online: 17 NOV 2009 | DOI: 10.1002/ejoc.200901101

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Alkynes reacted with thiols in water to give vicinal dithioethers, and non-terminal propargyl alcohols reacted with phenyl thiols to produce a highly regio and stereoselective monohydrothiolation product, (E)-alkenyl thioether.

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