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Jun Zhou, Guang-Liang Zhang, Jian-Ping Zou and Wei Zhang Synthesis of Phosphonylated and Thiolated Indenones by Manganese(III)-Mediated Addition of Phosphorus- and Sulfur-Centered Radicals to 1,3-Diarylpropynones European Journal of Organic Chemistry 2011

Version of Record online: 24 MAY 2011 | DOI: 10.1002/ejoc.201100486

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Phosphorus- or sulfur-centered radicals generated from the reaction of manganese(III) acetate with dialkyl phosphonates or arylthiols undergo selective additions toconjugated alkynes followed by cyclization and rearomatization to afford 2-phosphonyl or 2-thioaryl-substituted indenones in fair to good yields.

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