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Valentine P. Ananikov, Julia V. Ivanova, Levon L. Khemchyan and Irina P. Beletskaya Unusual Control of Reaction Selectivity through a Subtle Change in the Ligand: Proof of Concept and Application in Pd-Catalyzed C–P Bond Formation European Journal of Organic Chemistry 2012

Version of Record online: 31 MAY 2012 | DOI: 10.1002/ejoc.201200342

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The steric effect of phosphane ligands upon coordination to a metal center can be controlled by switching between unrestricted and restricted rotation modes. The efficiency of this concept was demonstrated in a study on the mechanisms of Pd-catalyzed hydrophosphorylation of alkynes, which was explored by using ESI-MS and NMR spectroscopy.

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