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Guobi Chai, Rong Zeng, Chunling Fu and Shengming Ma Iron-Catalyzed Diastereoselective Synthesis of α-(Methoxycarbonyl)allylsilanes European Journal of Organic Chemistry 2013

Version of Record online: 15 NOV 2012 | DOI: 10.1002/ejoc.201201209

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Treatment of 1-(trimethylsilyl)allene-1-carboxylates with Grignard reagents under iron catalysis conditions afforded stereodefined polysubstituted α-(methoxycarbonyl)allylsilanes in good to excellent yields. In addition, the products could be further applied to the stereocontrolled synthesis α,β-alkenoates, a β,γ-alkenoate, and an allylic fluoride.

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