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Riadh Dardouri, Héla Habli, Brahim Oujia and Florent Xavier Gadéa Ab Initio Diabatic energies and dipole moments of the electronic states of RbLi molecule Journal of Computational Chemistry 34

Version of Record online: 26 JUN 2013 | DOI: 10.1002/jcc.23363

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The calculation of the radiative lifetimes is carried out using Fermi's golden rule. The determined radiative lifetimes of the vibrational levels trapped in the 21Σ1+ state have an order of magnitude of nanoseconds. For this state, as the vibrational level increases, the radiative lifetime presents some oscillations; however, these are much weaker than for the nonradiative lifetime in which orders of magnitude vary.

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