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Judith Monnier, Ludovic Bellot-Gurlet, Denis Baron, Delphine Neff, Ivan Guillot and Philippe Dillmann A methodology for Raman structural quantification imaging and its application to iron indoor atmospheric corrosion products Journal of Raman Spectroscopy 42

Article first published online: 27 SEP 2010 | DOI: 10.1002/jrs.2765

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Using the spectra decomposition by linear combination of reference spectra, we propose to extract quantitative parameters from Raman hyperspectral maps in the case of solid-state samples. This approach is applied to ancient corroded iron samples coming from the Amiens cathedral (France) to establish the description and the composition of the corrosion system through quantitative phase mapping. The global phase quantities proposed will supply data for calculating some ‘protectivity ratio’ which could document the system stability.

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