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L. Desgranges, G. Baldinozzi, P. Simon, G. Guimbretière and A. Canizares Raman spectrum of U4O9: a new interpretation of damage lines in UO2 Journal of Raman Spectroscopy 43

Version of Record online: 20 OCT 2011 | DOI: 10.1002/jrs.3054

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The Raman spectrum of a pure-phase U4O9 is for the first time completely described and interpreted. The U4O9 Raman spectrum derives from the well characterised one of UO2. Besides reminiscent modes of UO2, a band at 630 cm-1, which has a specific response to polarised light, was interpreted as characteristic of clusters of interstitial oxygen atoms.

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