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Leonardo Puppulin, Masaya Kotaki, Morimasa Nakamura, Daisuke Iba, Ichiro Moriwaki and Giuseppe Pezzotti Raman tensor analysis of hexagonal polyoxymethylene and its application to study the molecular arrangement in highly crystalline electrospun nanofibers Journal of Raman Spectroscopy 43

Article first published online: 15 JUL 2012 | DOI: 10.1002/jrs.4116

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The orientation dependence in space of Raman-active A1 and E1 vibrational modes of the hexagonal structure of polyoxymethylene is discussed in terms of Raman tensor elements as intrinsic physical parameters of the lattice. An approach based on the introduction of orientation distribution functions is applied to quantitatively assess and compare on a statistical base the molecular orientation of two different types of polyoxymethylene nanofibers.

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