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M. Louviot, V. Boudon, D. Bermejo, R. Z. Martínez and L. Manceron High-resolution stimulated Raman spectroscopy and analysis of the ν1 band of osmium tetroxide Journal of Raman Spectroscopy 44

Article first published online: 11 AUG 2012 | DOI: 10.1002/jrs.4144

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The first high-resolution stimulated Raman spectrum of the ν1 totally symmetric stretching mode of OsO4 has been recorded. It allowed a refinement of the analysis of the ν13 dyad. A positive isotopic shift for ν1 indicates a perturbation by the nearby bending polyad.

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