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Dariusz Sobolewski, Edyta Proniewicz, Dominika Skołuba, Adam Prahl, Yukihiro Ozaki, Younkyoo Kim and Leonard M. Proniewicz Characterization of adsorption mode of new B2 bradykinin receptor antagonists onto colloidal Ag substrate Journal of Raman Spectroscopy 44

Article first published online: 10 JAN 2013 | DOI: 10.1002/jrs.4193

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In this study, we discussed the orientation and mode of adsorption of [D-Arg0, Hyp3,Thi5,8,L-Pip7]BK, Aaa[D-Arg0,Hyp3,Thi5,8,L-Pip7] BK, [D-Arg0,Hyp3,Thi5,D-Phe7,L-Pip8]BK, and Aaa[D-Arg0,Hyp3, Thi5,D-Phe7,L-Pip8]BK, potent B2 bradykinin receptor antagonists, adsorbed on a colloidal Ag surface, using SERS. To reveal the adsorption mechanism of these species from their SERS spectra, Fourier-transform-Raman spectra of the non-adsorbed molecules were measured and then compared with corresponding SERS spectra.

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