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Nicholas P. McKay, David L. Dettman, Robert T. Downs and Jonathan T. Overpeck On the potential of Raman-spectroscopy-based carbonate mass spectrometry Journal of Raman Spectroscopy 44

Version of Record online: 6 DEC 2012 | DOI: 10.1002/jrs.4218

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We investigated the potential of Raman spectroscopy for oxygen mass spectrometry in calcites by measuring the Raman spectra of a suite of synthesized calcite crystals. We found a 1:1 correspondence between the ratio of ν1 peak heights in the Raman spectra and the isotopic ratios measured by standard calcite mass spectrometry.

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