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H. Aouididi, M. Rotger, D. Bermejo, R.Z. Martínez and V. Boudon High-resolution stimulated Raman spectroscopy and analysis of the ν1/ν5 (C–H) stretching dyad of C2H4 Journal of Raman Spectroscopy 44

Article first published online: 7 DEC 2012 | DOI: 10.1002/jrs.4224

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The high-resolution stimulated Raman spectra of the ν15 C–H stretching bands of C2H4 have been recorded and analyzed by means of the tensorial formalism developed in Dijon for X2Y4 asymmetric-top molecules. A total of 689 lines (428 for ν5 and 261 for ν1) were assigned and fitted as a dyad including Coriolis coupling constants. We obtained a global root mean square deviation of 4.4 × 10−3 cm−1.

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