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Raúl Z. Martínez, Dionisio Bermejo, Gianfranco Di Lonardo and Luciano Fusina High-resolution Raman spectroscopy of ν2 and associated hot bands of 13CH12CH: global analysis of the anharmonic resonances Journal of Raman Spectroscopy 44

Article first published online: 3 FEB 2013 | DOI: 10.1002/jrs.4247

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The Raman spectrum of the 13CH12CH molecule in the region of its ν2 vibrational band has been recorded at high resolution, and five vibrational bands have been observed. A joint analysis of these bands and several previously observed infrared ones has been carried out, rendering a set of deperturbed molecular parameters. The ro-vibrational pattern of the stretching and stretching-bending combination states and an accurate description of the anharmonic resonances in this molecule have been obtained.

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