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Tsung-Han Yu, Chin-Hsian Ho, Cheng-You Wu, Ching-Hsuan Chien, Chia-Her Lin and Szetsen Lee Metal–organic frameworks: a novel SERS substrate Journal of Raman Spectroscopy 44

Version of Record online: 11 SEP 2013 | DOI: 10.1002/jrs.4378

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Without the aid of any metal colloids or enhancing agents, the surface-enhanced Raman scattering (SERS) signals of methyl orange adsorbed in metal–organic frameworks (MOFs) were observed and even remained active if the organic linkers in MOFs were completely removed by high temperature and O2 plasma treatments. It implies that the SERS active site is at the metal oxide clusters.

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