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Boris A. Kolesov Experimental determination of vibrational anharmonic contributions Journal of Raman Spectroscopy 44

Version of Record online: 6 NOV 2013 | DOI: 10.1002/jrs.4409

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A novel method for the determination of separate anharmonic terms involving the anharmonicity of zero-point motion and phonon itself and thus an estimation of unrenormalized phonon energy can be used to obtain anharmonic contributions for any vibrational mode, any types of chemical bonds (van der Waals, hydrogen, ionic, and covalent bonds), and any types of vibrational motion (translations, librations, bendings, and stretchings).

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