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Yi Yang, Sheng Pan, Jia-Dan Xue, Xuming Zheng, Wei-Hai Fang and David Lee Phillips Structural dynamics of 4-cyanobenzaldehyde in S2(ππ*) state Journal of Raman Spectroscopy 45

Article first published online: 18 DEC 2013 | DOI: 10.1002/jrs.4420

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The structural dynamics of 4-cyanobenzaldehyde was studied by using resonance Raman spectroscopy and quantum mechanical calculations. The conical intersection between S1(nOπ3) and S22π3) states of p-CNB was determined. The ν16 Raman band is the signature for the existence of the [S1(nOπ3)/S21π2π3π4)] conical intersection.

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