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Julian J. Schuster, Stefan Will, Alfred Leipertz and Andreas Braeuer Deconvolution of Raman spectra for the quantification of ternary high-pressure phase equilibria composed of carbon dioxide, water and organic solvent Journal of Raman Spectroscopy 45

Article first published online: 25 FEB 2014 | DOI: 10.1002/jrs.4451

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An evaluation strategy to extract the phase equilibrium data of ternary systems composed of CO2, water and organic solvent at elevated pressures from their Raman spectra is presented. The strategy is based on the combination of fitting weighted Raman spectra of the pure compounds to the measured spectra and deconvoluting Raman peaks in Gaussian and Voigt profiles.

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