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Milko N. Iliev and Hans Schmid Raman spectroscopy of M3B7O13X boracites (M = Cr,Co,Ni,Cu,Zn,Cd; X = Cl,Br,I) Journal of Raman Spectroscopy 45

Version of Record online: 3 MAR 2014 | DOI: 10.1002/jrs.4458

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Raman spectra of 16 single crystal boracites M3B7O13X (M = Cr,Co,Ni,Cu,Zn,Cd; X = Cl,Br,I) are studied over a broad temperature range covering different phases (cubic, orthorhombic, monoclinic, and trigonal. Special attention is paid to the temperature hysteresis near the transitions and the dependence of transition temperature on the direction of crystal growth for the same material.

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