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Oktay Uzun, Amitav Sanyal, Youngdo Jeong and Vincent M. Rotello Molecular Recognition Induced Self-Assembly of Diblock Copolymers: Microspheres to Vesicles Macromolecular Bioscience 10

Version of Record online: 16 APR 2010 | DOI: 10.1002/mabi.200900455

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The diblock copolymers with diamidopyridine give highly organized microstructures, when they are mixed with the complementary thymine functionalized monoblock copolymers. These microspheres can be efficiently crosslinked via photochemical [2πs + 2πs] cycloaddition with the resultant morphology change into vesicular structures. Through choice of block structure and length a wide variety of solution-phase structures and microstructured solids have been produced.

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