Oktay Uzun, Amitav Sanyal, Youngdo Jeong and Vincent M. Rotello Molecular Recognition Induced Self-Assembly of Diblock Copolymers: Microspheres to Vesicles Macromolecular Bioscience 10
The diblock copolymers with diamidopyridine give highly organized microstructures, when they are mixed with the complementary thymine functionalized monoblock copolymers. These microspheres can be efficiently crosslinked via photochemical [2πs + 2πs] cycloaddition with the resultant morphology change into vesicular structures. Through choice of block structure and length a wide variety of solution-phase structures and microstructured solids have been produced.
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