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Brad P. Morgan, Robert J. Gilliard Jr., Rahul S. Loungani and Rhett C. Smith Poly(p-phenylene ethynylene) Incorporating Sterically Enshrouding m-Terphenyl Oxacyclophane Canopies Macromolecular Rapid Communications 30

Version of Record online: 22 JUN 2009 | DOI: 10.1002/marc.200900160

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Novel canopies comprised by m-terphenyl oxacyclophane units have been installed about a π-conjugated polymers backbone to shield one side of the π-system from interchain interactions and to scaffold π-stacking between the polymer and a canopy aryl ring. The canopy allowed for an enhanced kinetic response to vapors of explosives and explosive simulant nitroorganics such as TNT due to enhanced permeability.

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