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Mahriah E. Alf, Paul D. Godfrin, T. Alan Hatton and Karen K. Gleason Sharp Hydrophilicity Switching and Conformality on Nanostructured Surfaces Prepared via Initiated Chemical Vapor Deposition (iCVD) of a Novel Thermally Responsive Copolymer Macromolecular Rapid Communications 31

Article first published online: 22 NOV 2010 | DOI: 10.1002/marc.201000452

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A thermally responsive polymer based onN-isopropylacrylamide (NIPAAm) with a sharp lower critical solution temperature (LCST) transition for facile, conformal, and substrate independent surface modification is presented. The novel polymer, p(NIPAAm-co-DEGDVE), synthesized via initiated chemical vapor deposition (iCVD), exhibits a relatively sharp LCST of ≈28.5±0.3 °C as determined via quartz crystal microbalance with dissipation monitoring (QCM-D).

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