Ryohei Kakuchi, Mirela Zamfir, Jean-François Lutz and Patrick Theato Controlled Positioning of Activated Ester Moieties on Well-Defined Linear Polymer Chains Macromolecular Rapid Communications 33
The successful sequence-controlled installation of an activated ester using a newly designed monomer pentafluorophenyl 4-maleimidobenzoate (PFP-MI) was demonstrated. PFP-MI is kinetically installed at an early stage of a nitroxide-mediated polymerization (namely, near the α-chain end) and in the middle of a PS chain. In addition, successful installation of apolar and polar functional groups is achieved via post-polymerization functionalization process.
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