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Shengwen Yuan, Desiree White, Alex Mason, Briana Reprogle, Magali S. Ferrandon, Luping Yu and Di-Jia Liu Improving Hydrogen Adsorption Enthalpy Through Coordinatively Unsaturated Cobalt in Porous Polymers Macromolecular Rapid Communications 33

Version of Record online: 30 JAN 2012 | DOI: 10.1002/marc.201100797

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A porous organic polymer functionalized with bipyridine–cobalt complexes is prepared through copolymerization of a spirobifluorene and a bipyridine monomers using cobalt carbonyl as catalysts and coordination agent. Hydrogen adsorption enthalpy increases by over 30% upon removal of the carbonyl ligand and CO2 from the porous network by a simple thermal treatment

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