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Gaëlle Le Fer, Julien Babinot, Davy-Louis Versace, Valérie Langlois and Estelle Renard An Efficient Thiol-Ene Chemistry for the Preparation of Amphiphilic PHA-Based Graft Copolymers Macromolecular Rapid Communications 33

Version of Record online: 7 SEP 2012 | DOI: 10.1002/marc.201200485

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A simple and efficient method to prepare thermosensitive graft polyhydroxyalkaoate (PHA) is presented. Terminal amino groups of Jeffamine are turned into thiol groups by a reaction with N-acetylhomocysteine. Subsequent grafting of ω-thiol Jeffamine on unsaturated PHA is achieved via photoinduced thiol-ene addition, leading to amphiphilic copolymers.

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