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Qiang Fu, Jing M. Ren, Shereen Tan, Jiangtao Xu and Greg G. Qiao Synthesis of Novel Core Cross-Linked Star-Based Polyrotaxane End-Capped via “CuAAC” Click Chemistry Macromolecular Rapid Communications 33

Article first published online: 11 SEP 2012 | DOI: 10.1002/marc.201200489

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A novel cyclodextrin-based star polyrotaxane is prepared via the inclusion complexation of star polymer precursors with α-cyclodextrins, followed by an end-capping reaction via “click” chemistry with a modified chromophore. The resultant star polyrotaxane shows a unique core–shell structure by TEM micrograph as a result of considerable steric repulsion of the formed polyrotaxane arms.

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