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Gaohua Zhu, Lifen Zhang, Xiangqiang Pan, Wei Zhang, Zhenping Cheng and Xiulin Zhu Facile Soap-Free Miniemulsion Polymerization of Methyl Methacrylate via Reverse Atom Transfer Radical Polymerization Macromolecular Rapid Communications 33

Version of Record online: 28 SEP 2012 | DOI: 10.1002/marc.201200492

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A facile soap-free miniemulsion polymerization of methyl methacrylate is successfully carried out via a reverse atom transfer radical polymerization (ATRP) technique, using a water-soluble potassium persulfate or V-50 both as the initiator and the stabilizer, and using an oil-soluble Cu(S2CN(C4H9)2)2 as the catalyst without adding any additional ligand. The results showed the “living”/controlled characteristics of ATRP and a good colloidal stability of the resultant latexes.

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