Andreas Mautner, Xiaohua Qin, Barbara Kapeller, Guenter Russmueller, Thomas Koch, Juergen Stampfl and Robert Liska Efficient Curing of Vinyl Carbonates by Thiol-Ene Polymerization Macromolecular Rapid Communications 33
Vinyl carbonates exhibit low toxicity together with good mechanical properties, which qualifies them to be a potential alternative to state-of-the-art (meth)acrylates. A drawback of a certain class of them containing easily abstractable hydrogens is their moderate reactivity. With the help of thiol-ene polymerization, we are able to improve the reactivity enormously up to the level of acrylates.
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