Kiarash Vakhshouri and Enrique D. Gomez Effect of Crystallization Kinetics on Microstructure and Charge Transport of Polythiophenes Macromolecular Rapid Communications 33
The crystallization kinetics can affect the microstructure and consequently charge transport of polythiophenes by changing the density of tie molecules. Rapid crystallization of P3HT and PBTTT results in higher density of tie molecules and higher charge carrier mobility. This suggests that controlling the crystallization kinetics might be an important factor for maximizing the charge mobility in semicrystalline polythiophene thin films.
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