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Michael Sommer and Hartmut Komber Spiropyran Main-Chain Conjugated Polymers Macromolecular Rapid Communications 34

Article first published online: 21 NOV 2012 | DOI: 10.1002/marc.201200688

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The synthesis of the first main-chain conjugated polymers containing spiropyran (SP) and dioctylfluorene (F8) units is presented. Detailed nuclear magnetic resonance (NMR) characterizations reveal a random orientation of the non-symmetric SP unit in the chain, and are used to follow the ultrasound-induced isomerization process.

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