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Tao Tang, Guoqiang Ding, Tingting Lin, Hong Chi, Chen Liu, Xuehong Lu, FuKe Wang and Chaobin He Near-Infrared Responsive Conjugated Polymers to 1.5 μm and Beyond: Synthesis and Electrochromic Switching Application Macromolecular Rapid Communications 34

Version of Record online: 27 DEC 2012 | DOI: 10.1002/marc.201200695

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Near-infrared responsive conjugated polymers with absorption up to 1.5 μm and above are designed and synthesized. DFT calculations attribute the near-infrared absorption to intra-molecular charge transfer on the polymer backbone. Electrochromic devices based on these polymers show a ten-fold enhancement in electrochromic contrast and significantly improved stability in the presence of TFA.

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