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Ramón Cervera-Procas, Carlos Sánchez-Somolinos, José L. Serrano and Ana Omenat A Polymer Network Prepared by the Thiol-yne Photocrosslinking of a Liquid Crystalline Dendrimer Macromolecular Rapid Communications 34

Version of Record online: 16 JAN 2013 | DOI: 10.1002/marc.201200730

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Easy to process polymeric materials may be prepared by the photocrosslinking of multifunctional dendrimers. A liquid crystalline dendrimer bearing azobenzene groups and alkyne-terminated units are photopolymerized with a tetrathiol agent to afford an oriented polymer film, which maintains the liquid crystalline order and responds to the light suffering a photoinduced deformation.

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