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Tatsuo Kimura Macroporous Oxide Platforms Templated by Non-Close-Packed Spherical Copolymer Aggregates Macromolecular Rapid Communications 34

Version of Record online: 20 DEC 2012 | DOI: 10.1002/marc.201200765

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Exclusive organic templating of macroporous oxide films is reported by using non-closed and lose packing of spherical copolymer aggregates, in combination with facile control of condensation degree/density of inorganic oxide frameworks during anisotropic shrinkage. Unique macroporous oxide films, mainly titania showing highly porous, crystalline, and versatile properties, can be fabricated with continuous design from unusual 3-D net-shape (macroreticular) to tunable spherical macrostructures.

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