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Ban Xuan Dong, Yoshihiro Honmou, Hideaki Komiyama, Shu Furumaki, Tomokazu Iyoda and Martin Vacha Conjugated Polymer Chains Confined in Vertical Nanocylinders of a Block-Copolymer Film: Preparation, Characterization, and Optoelectronic Function Macromolecular Rapid Communications 34

Version of Record online: 15 JAN 2013 | DOI: 10.1002/marc.201200766

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Hybrid materials composed of a phase-separated block copolymer and oriented chains of phenylenevinylene (PPV) family polymers are reported. Confinement of the PPV chains into vertical cylinders of nanometer diameter results in large absorption anisotropy. The hybrid films show electroluminescence from the PPV chains at minute doping concentrations and exhibit increased electron transport along the single PPV chains.

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