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Jon Hollinger, J. Sun, D. Gao, D. Karl and D. S. Seferos Statistical Conjugated Polymers Comprising Optoelectronically Distinct Units Macromolecular Rapid Communications 34

Version of Record online: 17 JAN 2013 | DOI: 10.1002/marc.201200777

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Poly(3-heptylselenophene)-stat-poly(3-hexylthiophene) is synthesized, characterized, and fabricated into photovoltaic devices. The copolymers are crystalline despite the random distribution of units along the backbone. Optoelectronic properties of the copolymer are an approximate average of the corresponding homopolymers, while the morphological properties are distinct.

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