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Alexander S. Quick, Joachim Fischer, Benjamin Richter, Thomas Pauloehrl, Vanessa Trouillet, Martin Wegener and Christopher Barner-Kowollik Preparation of Reactive Three-Dimensional Microstructures via Direct Laser Writing and Thiol-ene Chemistry Macromolecular Rapid Communications 34

Version of Record online: 23 JAN 2013 | DOI: 10.1002/marc.201200796

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Reactive 3D microstructures are fabricated by two-photon direct laser writing of a tetra-functional thiol with a tetra-functional allyl ether via radical thiol-ene polymerization, expressing residual thiol functionalities on the surface of the structure. These functionalities can be readily addressed by thiol-Michael addition reactions, evidenced by fluorescence microscopy and X-ray photoelectron spectroscopy.

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