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Alan O. Burts, Angela X. Gao and Jeremiah A. Johnson Brush-First Synthesis of Core-Photodegradable Miktoarm Star Polymers via ROMP: Towards Photoresponsive Self-Assemblies Macromolecular Rapid Communications 35

Version of Record online: 22 NOV 2013 | DOI: 10.1002/marc.201300618

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The brush-first ROMP method is applied to the synthesis of two- and three-miktoarm brush-arm star polymers (BASPs) with photodegradable cores. These particles undergo intramolecular phase-segregation to form Janus-like assemblies. UV irradiation induces core degradation, which switches the assembly pathway from Janus particles to micelles.

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