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Alejandro Trejos, Dr. Luke R. Odell and Prof. Mats Larhed Development of Stereocontrolled Palladium(II)-Catalyzed Domino Heck/Suzuki β,α-Diarylation Reactions with Chelating Vinyl Ethers and Arylboronic Acids ChemistryOpen 1

Article first published online: 28 FEB 2012 | DOI: 10.1002/open.201100010

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Watch out for water! The stereoselective diarylation of three different metal-coordinating, cyclic methylamino vinyl ethers is described. The reaction proceeds via a chelation-controlled Heck/Suzuki diarylation pathway, and represents the first example of a stereoselective, oxidative Heck/Suzuki domino reaction.

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