Sori Son, Sun Young Kim and Prof. Young Keun Chung Rhodium-Catalyzed Rearrangement Reaction of Azabicyclo[4.1.0]heptenes bearing Cyclopropyl and Aryl Groups to Arylhexahydroisoquinolines ChemistryOpen 1
Let′s rearrange! Rh(PPh3)2(CO)Cl/AgBF4 has been found to be an efficient catalytic system in the rearrangement of azabicyclo[4.1.0]heptenes having an aryl and a cyclopropyl group in the 1- and 6-position, respectively. This has led to the development of an efficient and simple method for the synthesis of arylhexahydroisoquinolines.
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