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Dr. Fateh V. Singh, Dr. Julia Rehbein and Prof. Dr. Thomas Wirth Facile Oxidative Rearrangements Using Hypervalent Iodine Reagents ChemistryOpen 1

Article first published online: 6 NOV 2012 | DOI: 10.1002/open.201200037

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Rearranged by iodine: Aromatic substituents migrate in a novel oxidative cyclization. Calculations highlight the cationic nature of the intermediates in the rearrangement. The fast access to heavily substituted furanones is used for the synthesis of biologically active derivatives.

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