Dr. Fateh V. Singh, Dr. Julia Rehbein and Prof. Dr. Thomas Wirth Facile Oxidative Rearrangements Using Hypervalent Iodine Reagents ChemistryOpen 1
Rearranged by iodine: Aromatic substituents migrate in a novel oxidative cyclization. Calculations highlight the cationic nature of the intermediates in the rearrangement. The fast access to heavily substituted furanones is used for the synthesis of biologically active derivatives.
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