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Barbara Ganisl and Dr. Kathrin Breuker Does Electron Capture Dissociation Cleave Protein Disulfide Bonds? ChemistryOpen 1

Article first published online: 30 NOV 2012 | DOI: 10.1002/open.201200038

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Runner-up! Disulfide bond cleavage comes second in gas phase radical ion chemistry. Cleavage of N[BOND]Cα backbone bonds is preferred over disulfide bond cleavage in electron capture dissociation (ECD) of peptides and proteins, but disulfide bonds can be cleaved by vibrational excitation or secondary radical reactions.

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