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Dr. Torben Birk Fluoride as Ligand: Chemistry of Some New Terminal and Bridged Systems ChemistryOpen 2

Version of Record online: 29 JAN 2013 | DOI: 10.1002/open.201200046

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Fluorine is unique! A synthesis method for polynuclear systems with bridging fluorido ligands has been developed. The method is based on anchoring and protection of the fluorido ligand by initial coordination to a robust metal center (e.g., CrIII) and subsequent use of the robust fluoride complex for construction of more complicated polynuclear structures.

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