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Marc A. Hillmyer and Timothy P. Lodge Synthesis and self-assembly of fluorinated block copolymers Journal of Polymer Science Part A: Polymer Chemistry 40

Version of Record online: 5 NOV 2001 | DOI: 10.1002/pola.10074

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Fluorinated block copolymers combine the unique properties of fluoropolymers and the intriguing self-assembly of hybrid macromolecules. The preparation of the title molecules by selective fluorination procedures and the effect of fluorine incorporation on the material thermodynamics are presented. The role of fluorination in determining block copolymer interactions in both the solid state and in solution and in ultimately exploiting fluorination to produce novel, higher order structures is central to our research efforts.

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